Dynamical van der Waals atom -surface interaction

Abstract: We obtained new nonrelativistic expression for the dynamical van der Waals atom -surface interaction energy of very convenient form for different applications. It is shown that classical result (Ferrell and Ritchie, 1980) holds only for a very slowly moving atom. In general case, the van der Waals atom -surface interaction energy manifests strong nonlinear dependence on velocity and distance. In close vicinity of metal and dielectric surfaces and velocities from 1 to 10 Bohr units the dynamical van der Waals potential proves to be significantly lower that in static case and goes to the static values with increasing distance and (or) decreasing velocity.