Cosmic-Ray-Driven Reaction and Greenhouse Effect of Halogenated Molecules: Culprits for Atmospheric Ozone Depletion and Global Climate Change

Abstract: This study is focused on the effects of cosmic rays (solar activity) and halogenated molecules (mainly chlorofluorocarbons-CFCs) on atmospheric O3 depletion and global climate change. Brief reviews are first given on the cosmic-ray-driven electron-induced-reaction (CRE) theory for O3 depletion and the warming theory of CFCs for climate change. Then natural and anthropogenic contributions are examined in detail and separated well through in-depth statistical analyses of comprehensive measured datasets. For O3 loss, new statistical analyses of the CRE equation with observed data of total O3 and stratospheric temperature give high linear correlation coefficients >=0.92. After removal of the CR effect, a pronounced recovery by 20~25% of the Antarctic O3 hole is found, while no recovery of O3 loss in mid-latitudes has been observed. These results show both the dominance of the CRE mechanism and the success of the Montreal Protocol. For global climate change, in-depth analyses of observed data clearly show that the solar effect and human-made halogenated gases played the dominant role in Earth climate change prior to and after 1970, respectively. Remarkably, a statistical analysis gives a nearly zero correlation coefficient (R=-0.05) between global surface temperature and CO2 concentration in 1850-1970. In contrast, a nearly perfect linear correlation with R=0.96-0.97 is found between global surface temperature and total amount of stratospheric halogenated gases in 1970-2012. Further, a new theoretical calculation on the greenhouse effect of halogenated gases shows that they (mainly CFCs) could alone lead to the global surface temperature rise of ~0.6 deg C in 1970-2002. These results provide solid evidence that recent global warming was indeed caused by anthropogenic halogenated gases. Thus, a slow reversal of global temperature to the 1950 value is predicted for coming 5~7 decades.