Ultrastrong and Ultrastable Metallic Glass

Abstract: The lack of thermal stability, originating from their metastable nature, has been one of the paramount obstacles that hinder the wide range of applications of metallic glasses. We report that the stability of a metallic glass can be dramatically improved by slow deposition at high temperatures. The glass transition and crystallization temperatures of the ultrastable metallic glass can be increased by 51 K and 203 K, respectively, from its ordinary glass state. The ultrastable metallic glass also shows ultrahigh strength and hardness, over 30 % higher than its ordinary counterpart. Atomic structure characterization reveals that the exceptional properties of the ultrastable glass are associated with abundance of medium range order. The finding of the ultrastable metallic glass sheds light on atomic mechanisms of metallic glass formation and has important impact on the technological applications of metallic glasses.