Foldy-Wouthuysen Transformation, Scalar Potentials and Gravity

Abstract: We show that care is required in formulating the nonrelativistic limit of generalized Dirac Hamiltonians which describe particles and antiparticles interacting with static electric and/or gravitational fields. The Dirac-Coulomb and the Dirac-Schwarzschild Hamiltonians, and the corrections to the Dirac equation in a non-inertial frame, according to general relativity, are used as example cases in order to investigate the unitarity of the standard and "chiral" approaches to the Foldy-Wouthuysen transformation, and spurious parity-breaking terms. Indeed, we find that parity-violating terms can be generated by unitary pseudo-scalar transformations ("chiral" Foldy-Wouthuysen transformations). Despite their interesting algebraic properties, we find that "chiral" Foldy-Wouthuysen transformations change fundamental symmetry properties of the Hamiltonian and do not conserve the physical interpretation of the operators. Supplementing the discussion, we calculate the leading terms in the Foldy-Wouthuysen transformation of the Dirac Hamiltonian with a scalar potential (of the (1/r)-form and of the confining radially symmetric linear form), and obtain compact expressions for the leading higher-order corrections to the Dirac Hamiltonian in a non-inertial rotating reference frame "Mashhoon term").