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Construction of the B88 exchange-energy functional in two dimensions

Published 25 Mar 2014 in cond-mat.str-el and physics.chem-ph | (1403.6297v1)

Abstract: We construct a generalized-gradient approximation for the exchange-energy density of finite two-dimensional systems. Guided by non-empirical principles, we include the proper small-gradient limit and the proper tail for the exchange-hole potential. The observed performance is superior to that of the two-dimensional local-density approximation, which underlines the usefulness of the approach in practical applications.

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