Non-Resonant Below-Bandgap Two-Photon Absorption in Quantum Dot Solar Cells

Abstract: We are the first to show with clear experimental results that photons that have energy lower than the transition energy between quantum dots states and valance band can still contribute greatly to the photocurrent via both one-photon absorption process (1PA) and two-photon absorption process (2PA). The tailing states function as both the energy states for low energy photon absorption and the photocarriers extraction pathway. One of the biggest advantages of our method is that it can clearly differentiate the photocurrent due to 1PA process and 2PA process. Both 1PA and 2PA photocurrent generation efficiency in an InAs/GaAs QD device with photon excitation at 1550 nm have been quantitatively evaluated.