Effect of delithiation on the dimer transition of the honeycomb-lattice ruthenate Li$_{2-x}$RuO$_3$

Abstract: The honeycomb-lattice ruthenate Li$2$RuO$_3$ is made heavily Li-deficient by chemical oxidation by iodine. The delithiation triggers a different phase Li${2-x}$RuO$_3$, the "D-phase", with superlattice. For the first time we disclose the magnetic and structural properties of the D-phase in the dimer-solid state. The low temperature magnetic susceptibility and the bond lengths indicate a bonding configuration consisting of both Ru$^{4+}$-Ru$^{4+}$ and Ru$^{5+}$-Ru$^{5+}$ dimers.