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Recommended Thermal Rate Coefficients for the C + H$_3^+$ Reaction and Some Astrochemical Implications

Published 30 Apr 2016 in astro-ph.IM and astro-ph.GA | (1605.00048v3)

Abstract: We have incorporated our experimentally derived thermal rate coefficients for C + H$_3+$ forming CH$+$ and CH$_2+$ into a commonly used astrochemical model. We find that the Arrhenius-Kooij equation typically used in chemical models does not accurately fit our data and use instead a more versatile fitting formula. At a temperature of 10 K and a density of 10$4$ cm${-3}$, we find no significant differences in the predicted chemical abundances, but at higher temperatures of 50, 100, and 300 K we find up to factor of 2 changes. Additionally, we find that the relatively small error on our thermal rate coefficients, $\sim15\%$, significantly reduces the uncertainties on the predicted abundances compared to those obtained using the currently implemented Langevin rate coefficient with its estimated factor of 2 uncertainty.

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