Role of photon recycling in perovskite solar cells

Abstract: Nearly perfect photon recycling helped GaAs cells achieve the highest efficiency ever reported for a solar cell. Recent reports of photon recycling in perovskite solar cells suggest that, once optimized, it may as well achieve GaAs-like performance. In this paper, we show that GaAs and perovskite cells recycle photons in different ways. First, although bare-perovskite has been shown to have lifetimes (~1us) in the radiative limit, non-radiative recombination at the transport layers restricts the solar cell operation far below the "photon-recycling" regime. GaAs cells have no such limitation. Second, even if the transport layers were optically and electrically perfect, the poor mobility of the perovskite layer would still restrict the optimum thickness ~1um. Thus, a very high quality mirror (reflectivity >96%) is required to utilize photon-recycling. The mirror reflectivity restriction was far more relaxed for the thicker (~2-3um) GaAs cells. Therefore, a nontrivial co-optimization of device geometry, mirror reflectivity, and material choice is necessary for achieving highest theoretical efficiency anticipated for perovskite cells.