Azetidinium Lead Iodide for Perovskite Solar Cells

Abstract: Hybrid organic-inorganic perovskites have been established as good candidate materials for emerging photovoltaics, with device efficiencies of over 22 % being reported. There are currently only two organic cations, methylammonium and formamidinium, which produce 3D perovskites with band gaps suitable for photovoltaic devices. Numerous computational studies have identified azetidinium as a potential third cation for synthesizing organic-inorganic perovskites, but to date no experimental reports of azetidinium containing perovskites have been published. Here we prepare azetidinium lead iodide for the first time and show that it is a stable, bright orange material that can be successfully used as the absorber layer in solar cells. We also show that it is possible to make mixed cation devices by adding the azetidinium cation to methylammonium lead iodide. Mixed azetidinium-methylammonium cells show improved performance and reduced hysteresis compared to methylammonium lead iodide cells.