Molding Molecular and Material Properties by Strong Light-Matter Coupling

Abstract: When atoms come together and bond, we call these new states molecules, and their properties determine many aspects of our daily life. Strangely enough, it is conceivable for light and molecules to bond, creating new hybrid light-matter states with far-reaching consequences for these strongly coupled materials. Even stranger, there is no real' light needed to obtain the effects, it simply appears from the vacuum, creatingsomething from nothing'. Surprisingly, the setup required to create these materials has become moderately straightforward. In its simplest form, one only needs to put a strongly absorbing material at the appropriate place between two mirrors, and quantum magic can appear. Only recently has it been discovered that strong coupling can affect a host of significant effects at a material and molecular level, which were thought to be independent of the `light' environment: phase transitions, conductivity, chemical reactions, etc. This review addresses the fundamentals of this opportunity: the quantum mechanical foundations, the relevant plasmonic and photonic structures, and a description of the various applications, connecting materials chemistry with quantum information, nonlinear optics and chemical reactivity. Ultimately, revealing the interplay between light and matter in this new regime opens attractive avenues for many applications in the material, chemical, quantum mechanical and biological realms.