Excitonic Complexes and Optical Gain in Two-Dimensional Molybdenum Ditelluride Well below Mott Transition

Abstract: Strong Coulomb interaction in 2D materials provides unprecedented opportunities for studying many key issues of condensed matter physics, such as co-existence and mutual conversions of excitonic complexes, fundamental optical processes associated with their conversions, and their roles in the celebrated Mott transition. Recent lasing demonstrations in 2D materials raise important questions about the existence and origin of optical gain and possible roles of excitonic complexes. While lasing occurred at extremely low densities dominated by various excitonic complexes, optical gain was observed in the only experiment at densities several orders of magnitude higher, exceeding the Mott density. Here, we report a new gain mechanism involving charged excitons or trions well below the Mott density in 2D molybdenum ditelluride. Our combined experimental and modeling study not only reveals the complex interplays of excitonic complexes well below the Mott transition, but also provides foundation for lasing at extremely low excitation levels, important for future energy efficient photonic devices.