Enhanced ponderomotive force in graphene due to interband resonance

Abstract: We analyze intrinsic nonlinearities in two-dimensional polaritonic materials interacting with an optical wave. Focusing on the case of graphene, we show that the second-order nonlinear optical conductivity due to carrier density fluctuations associated with the excitation of a plasmon polariton is closely related to the ponderomotive force due to the oscillating optical field. This relation is first established through an elegant thermodynamic approach for a Drude-like plasma, in the frequency range where intraband scattering is the dominant contribution to conductivity. Subsequently, we extend our analysis to the interband regime, and show that for energies approximately half the Fermi energy, the intraband contribution to the ponderomotive force diverges. In practice, thermal broadening regularizes this divergence as one would expect, but even at room temperature typically leaves a strong ponderomotive enhancement. Finally, we study the impact of nonlocal corrections and find that nonlocality does not lead to further broadening (as one would expect in the case of Landau damping), but rather to a splitting of the ponderomotive interband resonance. Our analysis should prove useful to the open quest for exploiting nonlinearities in graphene and other two-dimensional polaritonic materials, through effects such as second harmonic generation and photon drag.