Explosion Dynamics of Methane Clusters Irradiated by 38 nm XUV Laser Pulses

Abstract: We have studied the explosion dynamics of methane clusters irradiated by intense, femtosecond, 38 nm (32.6 eV) XUV laser pulses. The ion time-of-flight spectrum measured with a Wiley-McLaren-type time-of-flight spectrometer reveals undissociated molecular $\textrm{CH}_4^+$ ions, fragments which are missing hydrogen atoms due to the breakage of one or more C-H bonds $(\textrm{CH}_3^+, \textrm{CH}_2^+ \ \textrm{and}\ \textrm{CH}^+)$ and the recombination product $\textrm{CH}_5^+$. Also visible on the time-of-flight traces are atomic and molecular hydrogen ions $(\textrm{H}^+ \textrm{and}\ \textrm{H}_2^+)$, carbon ions, and larger hydrocarbons such as $\textrm{C}_2 \textrm{H}_2^+$ and $\textrm{C}_2\textrm{H}_3^+$. No doubly-charged parent ions $(\textrm{CH}_4^{2+})$ were detected. The time-of-flight results show that total and relative ion yields depend strongly on cluster size. The absolute yields of $\textrm{CH}^+_5$ and $\textrm{H}^+$ scale linearly with the yields of the other generated fragments up to a cluster size of $\langle\textrm{N}\rangle=70,000 \ \textrm{molecules}$, then begin to decrease, whereas the yields of the $\textrm{CH}_n^+(n=1-4) $ fragments plateau at this cluster size. The behavior of $\textrm{H}^+$ may be understood through the electron recombination rate, which depends on the electron temperature and the cluster average charge. Moreover, the $\textrm{CH}_5^+$ behavior is explained by the depletion of both $\textrm{CH}_4^+$ and $\textrm{H}^+$ via electron-ion recombination in the expanding nanoplasma.