The Cox-Voinov law for traveling waves in the partial wetting regime
Abstract: We consider the thin-film equation $\partial_t h + \partial_y \left(m(h) \partial_y3 h\right) = 0$ in ${h > 0}$ with partial-wetting boundary conditions and inhomogeneous mobility of the form $m(h) = h3+\lambda{3-n}hn$, where $h \ge 0$ is the film height, $\lambda > 0$ is the slip length, $y > 0$ denotes the lateral variable, and $n \in (0,3)$ is the mobility exponent parameterizing the nonlinear slip condition. The partial-wetting regime implies the boundary condition $\partial_y h = \mathrm{const.} > 0$ at the triple junction $\partial{h > 0}$ (nonzero microscopic contact angle). Existence and uniqueness of traveling-wave solutions to this problem under the constraint $\partial_y2 h \to 0$ as $h \to \infty$ have been proved in previous work by Chiricotto and Giacomelli in [Commun. Appl. Ind. Math., 2(2):e-388, 16, 2011]. We are interested in the asymptotics as $h \downarrow 0$ and $h \to \infty$. By reformulating the problem as $h \downarrow 0$ as a dynamical system for the difference between the solution and the microscopic contact angle, values for $n$ are found for which linear as well as nonlinear resonances occur. These resonances lead to a different asymptotic behavior of the solution as $h\downarrow0$ depending on $n$. Together with the asymptotics as $h\to\infty$ characterizing the Cox-Voinov law for the velocity-dependent macroscopic contact angle as found by Giacomelli, the first author of this work, and Otto in [Nonlinearity, 29(9):2497-2536, 2016], the rigorous asymptotics of traveling-wave solutions to the thin-film equation in partial wetting can be characterized. Furthermore, our approach enables us to analyze the relation between the microscopic and macroscopic contact angle. It is found that the Cox-Voinov law for the macroscopic contact angle depends continuously differentiably on the microscopic contact angle.
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