Macroscopic production of spin-polarized hydrogen atoms from the IR-excitation and photodissociation of molecular beams

Abstract: We describe methods for the production of spin-polarized H and D atoms from the IR-excitation and photodissociation of molecular beams of HBr, HI, and ${\rm NH_{3}}$ isotopes, including optical excitation schemes with partial hyperfine resolution. We discuss the extent to which the production rates may approach the IR-laser production rates of ${\rm 10^{21}\, photons\, s^{-1}}$, and how the production rates of conventional methods of ${\sim}{\rm 10^{17} \, s^{-1}}$ may be surpassed significantly.