The Influence of Dimensionality on the Charge Density Wave Transition and Its Application on Mid-infrared Photodetection

Abstract: Two-dimensional charge density wave (CDW) materials received much attention for high responsivity and broadband photodetection in recent years, due to their collective electron transport and narrow bandgap. However, the high dark current density problem hinders their real application. Here we report a sharp CDW transition in quasi-1D (TaSe4)2I, and apply it for broadband photodetection. Especially at mid-infrared region, the device shows both high photo responsivity of 1.18e3 A/W and large light on-off ratio of 80, which is superior than 2D CDW TaS2 and most reported low-dimensional materials. The fact for such high performance lies on two aspects. One is the much lower dark current density resulted from the pseudo gap associated with 1D Luttinger liquid state, which is supported by finite size scaling of nonlinear I-V at variable temperatures and occurrence of 1D structural phase transition consolidated by In-situ Raman spectroscopy. The other is the high photocurrent associated with the Frohlich superconductivity state, manifested by an ultrasensitive switching, which can be only accessible in 1D CDW materials, in agreement with our density functional theory calculation. Our work thus reveals the pivotal role of dimensionality in CDW phase transition, and paves a way for implementing highly sensitive broadband photodetector.