The computational evidence for the crucial role of the dipole cross-correlations in the polar glass-forming liquids

Abstract: In this letter, we analyze the dipole-dipole correlations obtained from the molecular dynamics simulations for strongly- and weakly-polar model liquids. As a result, we found that cross-correlations contribution to the systems total dipole moment correlation function, which is directly measured in the dielectric spectroscopy experiment, is negligible for weakly-polar liquids. In contrast, the cross-correlations term dominates over the self-correlations one for examined strongly polar-liquid. Consequently, our studies strongly support the interpretation of the dielectric spectra nature of the glass forming liquids, recently proposed by Pabst et al.