Unsteady wetting of soft solids

Abstract: From hydrogels and plastics to liquid crystals, soft solids cover a wide array of synthetic and biological materials that play key enabling roles in advanced technologies such as 3D printing, soft robotics, wearable electronics, self-assembly, and bioartificial tissues. Their elasticity and stimuli-induced changes in mechanical, optical, or electrical properties offer a unique advantage in designing and creating new dynamically functional components for sensing, micro-actuation, colour changes, information, and mass transport. To harness the vast potential of soft solids, a thorough understanding of their reactions when exposed to liquids is needed. Attempts to study the interactions between soft solids and liquids have largely focused on the wetting of soft solids and its resulting deformation at equilibrium or in a quasi-static state. Here, we consider the frequently encountered case of unsteady wetting of a liquid on a soft solid and show that transient deformation of the solid is necessary to understand unsteady wetting behaviours. We find that the initial spreading of the liquid occurs uninterrupted in the absence of solid deformation. This is followed by intermittent spreading, in which transient deformation of the solid at the three-phase contact line (CL) causes the CL motion to alternate alternation between CL sticking and slipping. We identify the spreading rate of liquids and the viscoelastic reacting rate of soft solids as the two competing factors in dictating intermittent spreading. We formulate and validate experimentally the conditions required for the contact line to transition from sticking to slipping. By considering the growing deformation of soft solids as dynamic surface heterogeneities, our proposed conditions for stick-slip transition in unsteady wetting on soft solids broaden the classical theory on wetting hysteresis on rigid solids.