Supercooled Droplet Icing and Self-Jumping on Micro/nanostructured Surfaces: Role of Vaporization Momentum

Abstract: Phase change under reduced environmental pressures is key to understanding liquid discharge and propulsion processes for aerospace applications. A representative case is the sessile water droplets exposed to high vacuum, which experience complex phase change and transport phenomena that behave so differently than that under the atmosphere. Here, we demonstrate a previously unexplored aspect of the mechanism governing icing droplet self-launching from superhydrophobic surfaces when exposed to low pressures (~100 Pa). In contrast to the previously reported recalescence-induced local overpressure underneath the droplet that propels icing droplet self-jumping, we show that the progressive recalescence over the free surface plays a significant role in droplet icing and jumping. The joint contribution of the top-down vaporization momentum and bottom-up local overpressure momentum leads to vaporization-compression-detaching dynamics of the freezing droplets. We delineate the jumping velocity of the icing droplet by analyzing droplet vaporization mediated by freezing and substrate structuring, and reveal jumping direction coupled with the spatially probabilistic ice nucleation. Our study provides new insights into phase change of supercooled droplets at extreme conditions seen in aerospace and vacuum industries.