Photocatalytic oxidation in few-layer Tellurene for loss-invariant integrated photonic resonance trimming

Abstract: Two-dimensional materials with unique physicochemical properties promote photocatalytic activities. As the 2D material composites research studies the statistical average of complex catalytic behaviors, an integrated photonic platform allows clean and single flake level photo-catalytic investigations with precisely quantified photocatalytic activities. In this paper, we track fluence-dependent photo-oxidation in two-dimensional Tellurene (2D Te) by the evanescently coupled micro-resonator. Nearly 32 perent of oxidation is achieved in 10 nm 2D Te flake, compared to only 4.5% oxidation in 30 nm sample, probed by the resonance shift in silicon microring resonators (MRRs) substrate. The wider bandgap in the few layers of 2D Te allows faster charge transfer to adsorbed oxygen for a more efficient photocatalytic redox reaction. The photo-oxidation in hybrid 2D Te results in an invariant lineshapes of optical transmission resonance for wavelength trimming (more than 3 times resonance bandwidth). The low threshold power, near-infrared, and in-waveguide resonance trimming scheme is compatible with most integrated photonic setups for easy fixing the nanofabrication-induced random resonance deviation for integrated photonic circuit applications in wavelength-division-multiplexing systems and spin qubits quantum computing.