Investigating the OH-H2 relation in diffuse Galactic clouds

Abstract: We investigate the correlation between OH and H2 column densities in diffuse Galactic clouds, in order to identify potential molecular tracers of interstellar H2. For this, we analyse near-UV spectra extracted from the ESO/VLT archives towards seventeen sightlines (five of them new) with known N(H2), along with nine sightlines with no H2 information. N(OH) shows only marginal correlation with N(H2) (10$^{20}$ to 2 x 10$^{21}$ cm$^{-2}$), at the 95 per cent confidence level. We use orthogonal distance regression analysis to obtain N(OH)/N(H2) = (1.32+/-0.15) x 10$^{-7}$, which is ~ 33 per cent higher than the previous estimates based on near-UV data. We also obtain N(CH)/N(H2) = (3.83+/-0.23) x 10$^{-8}$ and a significant correlation between N(OH) and N(CH), with N(OH) = (2.61+/-0.19) x N(CH), both of which are consistent with previous results. Comparison with predictions of numerical models indicate that OH absorption arises from diffuse gas (nH ~ 50 cm$^{-3}$) illuminated by radiation fields ~ 0.5-5 G0, while CH is associated with higher density of 500 cm$^{-3}$. We posit that the apparent dichotomy in the properties of the diffuse clouds giving rise to OH and CH absorption could be due to either (a) the presence of multiple spectroscopically unresolved clouds along the line-of-sight, or, (b) density gradients along the line-of-sight within a single cloud.