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The effect of LPSO phase on the high-temperature oxidation of a stainless Mg-Y-Al alloy

Published 26 Nov 2023 in cond-mat.mtrl-sci | (2311.15182v2)

Abstract: In this study, we investigated the oxidation of the Mg-11Y-1Al alloy at 500{\deg}C in an Ar-20%O2 environment. Multiscale analysis showed the network-like long-period stacking ordered (LPSO) phase transformed into needle-like LPSO and polygonal Mg24Y5 phases, leading to the formation of a high-dense network of needle-like oxides at the oxidation front. These oxides grew laterally along the oxide/matrix interfaces, forming a thicker, continuous scale that effectively blocked elemental diffusion. Hence, the preferential oxidation along the needle-like LPSO is believed to accelerate the formation of a thicker and continuous oxide scale, further improving the oxidation resistance of the Mg-11Y-1Al alloy.

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