Investigating Cathode Electrolyte Interphase Formation in NMC 811 Primary Particles Through Advanced 4D-STEM ACOM Analysis

Abstract: The study focuses on NMC811, a promising material for high-capacity batteries, and investigates the challenges associated with its use, specifically the formation of the Cathode Electrolyte Interphase (CEI) layer due to chemical reactions. This layer is a consequence of the position of the LUMO energy level of NMC811 that is close to the HOMO level of liquid electrolyte, resulting in electrolyte oxidation and cathode surface alterations during charging. A stable CEI layer can mitigate further degradation by reducing the interaction between the reactive cathode material and the electrolyte. Our research analyzed the CEI layer on NMC811 using advanced techniques such as 4D-STEM ACOM and STEM- EDX, focusing on the effects of different charging voltages (4.3 V and 4.5 V). The findings revealed varying degrees of degradation and the formation of a fluorine-rich layer on the secondary particles. Detailed analysis showed the composition of this layer differed based on the voltage: only LiF at 4.5 V and a combination of LiF and LiOH at 4.3 V. Despite LiF's known stability as a CEI protective layer, our observations indicate it does not effectively prevent degradation in NMC811. The study concludes that impurities and unwanted chemical reactions leading to suboptimal CEI formation are inevitable. Therefore, future efforts should focus on developing protective strategies for NMC811, such as the use of specific additives or coatings.