Switching response and ionic hysteresis in organic electrochemical transistors

Abstract: Hysteresis in organic electrochemical transistors (OECT) is a basic effect in which the measured current depends on the voltage sweep direction and velocity. This phenomenon has an important impact on different aspects of the application of OECT, such as the switching time and the synaptic properties for neuromorphic applications. Here we address the combined ionic and electronic kinetic effects that cause the dominant hysteresis effects. We use a combination of tools consisting on basic analytical models, advanced 2D drift-diffusion simulation, and the experimental measurement of a Poly(3-hexylthiophene) (P3HT) OECT, working in an accumulation mode. We develop a general transmission line model considering drift electronic transport and ionic injection and diffusion from the electrolyte. We provide a basic classification of the transient response to a voltage pulse, according to the dominant ionic or electronic relaxation time, and the correspondent hysteresis effects of the transfer curves according to the general categories of inductive and capacitive hysteresis. These are basically related to the main control phenomenon, either the vertical diffusion of ions during doping and dedoping, or the equilibration of electronic current along the channel length.