Non-Markovian Quantum Heat Statistics with the Reaction Coordinate Mapping

Abstract: The definition of heat in quantum mechanics is ambiguous. Complications arise in particular when the coupling between a quantum system and an environment is non-negligible, as the boundary between the two becomes blurred, making the distinction between system and environment difficult to draw. The reaction coordinate mapping can be used in such regimes to redraw the boundary between the system and environment. Here we combine the reaction coordinate technique with a two-point measurement protocol to compare two different definitions of heat: energetic changes in the full environment Hamiltonian (prior to the mapping), and energetic changes in the residual environment Hamiltonian (after the mapping). We find that the latter definition displays behaviour more expected of a thermal environment in the highly non-Markovian regime considered.