Effects of Mischmetal Composition and Cooling Rates on the Microstructure and Mechanical Properties of Al-(Ce, La, Nd) Eutectic Alloys

Abstract: This study investigates the substitution of cerium (Ce) with mischmetal (MM) in cast Al-MM alloys, focusing on microstructure, hardness, tensile and compression properties, creep resistance, and coarsening resistance. Al-MM alloys with various MM compositions (Ce, Ce-50La, Ce-33La, and Ce-27La-19Nd, weight percent) exhibit near-eutectic and hyper-eutectic microstructures for Al-9MM and Al-12MM compositions, respectively, with similar as-cast hardness (~525 MPa). All Al-9MM alloys show tensile yield stress ~55 MPa, ultimate tensile strength ~130 MPa, and fracture strain ~8%.The microstructural and mechanical properties consistency demonstrates the flexibility of MM compositions in Al-MM alloys. Al-9MM exhibits excellent coarsening resistance, with minimal hardness reduction when exposed to 300 and 350 C for up to 11 weeks, and a modest ~15% hardness reduction at 400 C for 8 weeks, outperforming eutectic Al-12.6Si and Al-6.4Ni alloys. Additionally, Al-9MM shows higher creep resistance at 300 C compared to most precipitate-strengthened Al-Sc-Zr and solid-solution-strengthened Al-Mg/Mn alloys, but is outperformed by eutectic-strengthened Al-6.4Ni and Al-10Ce-5Ni alloys.The effect of casting cooling rate is investigated through wedge casting: Al-9Ce transitions from hypo- to hyper-eutectic as cooling rates decrease, while Al-12Ce consistently shows hyper-eutectic microstructures. Al11Ce3 lamellae become finer and more closely spaced with increasing cooling rates. Al-9Ce maintains steady hardness at high to moderate cooling rates but shows reduced hardness at lower rates, whereas Al-12Ce shows no change in hardness.With a 15% reduction in energy consumption and CO2 emissions, Al-Ce alloys where Ce is replaced with MM offer comparable mechanical properties and enhanced environmental benefits, highlighting the potential of MM as a sustainable alternative.