Scanning cavity OF-CEAS technique for rapid collection of high resolution spectra

Abstract: We present a modified approach to laser optical-feedback cavity-enhanced absorption spectroscopy. The technique involves continuously scanning the length of a high-finesse cavity to periodically lock a diode laser to the cavity resonance, resulting in a discrete set of transmission measurements that are evenly spaced in frequency. For a fixed laser bias, data can be collected spanning a spectral bandwidth equivalent to the free-spectral range of the cavity, with spectral resolution inversely proportional to the distance from the laser to cavity. The center frequency of this scan can be tuned by tuning the free-running laser frequency. We demonstrate the concept using a fiber-coupled 1578-nm laser and a scanning Fabry-Perot cavity to measure a series of weak CO2 absorption lines with a frequency resolution of 15.6 MHz and a noise equivalent absorption coefficient of 10-7 cm-1, limited by the moderate finesse (~5000) and short length (~5 cm) of the cavity. Individual CO2 line shapes can be measured with high resolution in a single scan that takes 67 ms. The approach has a combination of characteristics that are advantageous for in situ instruments, such as small size, high spectral resolution, fast data collection, and minimal components.