Computing sessile droplet shapes on arbitrary surfaces with a new pairwise force smoothed particle hydrodynamics model

Abstract: The study of the shape of droplets on surfaces is an important problem in the physics of fluids and has applications in multiple industries, from agrichemical spraying to microfluidic devices. Motivated by these real-world applications, computational predictions for droplet shapes on complex substrates -- rough and chemically heterogeneous surfaces -- are desired. Grid-based discretisations in axisymmetric coordinates form the basis of well-established numerical solution methods in this area, but when the problem is not axisymmetric, the shape of the contact line and the distribution of the contact angle around it are unknown. Recently, particle methods, such as pairwise force smoothed particle hydrodynamics (PF-SPH), have been used to conveniently forego explicit enforcement of the contact angle. The pairwise force model, however, is far from mature, and there is no consensus in the literature on the choice of pairwise force profile. We propose a new pair of polynomial force profiles with a simple motivation and validate the PF-SPH model in both static and dynamic tests. We demonstrate its capabilities by computing droplet shapes on a physically structured surface, a surface with a hydrophilic stripe, and a virtual wheat leaf with both micro-scale roughness and variable wettability. We anticipate that this model can be extended to dynamic scenarios, such as droplet spreading or impaction, in the future.