Epitaxial Sr-doped nickelate perovskite thin films and Ruddlesden-Popper phases grown by magnetron sputtering

Abstract: Sr-doped nickelate, Nd1-xSrxNiO3 (NSNO), perovskite thin films and Ruddlesden-Popper (RP) phases are actively investigated because of their physical properties, such as the metal-insulator transition and superconductivity. However, achieving epitaxial growth of NSNO perovskite and RP phase films in a sputtering system is challenging compared to pulsed laser deposition and molecular beam epitaxy, due to the difficulty in stabilizing nickel oxidation states and minimizing structural defects. Here, we used an off-axis radio frequency (RF) magnetron sputtering to fabricate epitaxial NSNO perovskite and RP phase thin films on SrTiO3 (001) substrates, systematically controlling the growth temperatures. We investigated the thermal stability of the perovskite phase and the structural and electronic characteristics of the RP phase films. These findings provide valuable insights into the synthesis of nickelate RP phase films using RF magnetron sputtering, paving the way for scalable thin films fabrication technologies.