Odd-parity Magnetism Driven by Antiferromagnetic Exchange

Abstract: Realizing odd-parity, time-reversal-preserving, non-relativistic spin splitting is a central goal for spintronics applications. We propose a group-theory-based microscopic framework to induce odd-parity spin splitting from coplanar antiferromagnetic (AFM) states without spin-orbit coupling (SOC). We develop phenomenological models for 421 conventional period-doubling AFM systems in non-symmorphic space groups and construct minimal microscopic models for 119 of these. We find that these AFM states can attain three possible competing ground states. These ground states all break symmetries in addition to those broken by the usual AFM order. Specifically, they give rise to either odd-parity spin-splitting, nematic order, or scalar odd-parity order related to multiferroicity. Our microscopic theories reveal that the odd-parity spin-splitting energy scale is generically large and further reveal that the scalar odd-parity order gives a non-zero Berry curvature dipole without SOC. We identify 67 materials in the Magndata database for which our theory applies. We provide DFT calculations on FeSe that reveal an $h$-wave spin splitting consistent with our symmetry arguments and apply our microscopic model to determine the non-relativistic Edelstein response for CeNiAsO.