The effect of elastic-plastic mismatch and interface proximity on the fracture toughness of Ti-TiN thin films

Abstract: Magnetron sputtered titanium nitride (TiN) thin films are widely used as protective coatings due to their high hardness, but suffer from inherent brittleness and low fracture toughness, limiting their applicability. The multilayering of TiN films with metallic titanium (Ti) interlayers in the form of bi-layer and tri-layer systems have been studied using microcantilever fracture tests. Plastic dissipation in the Ti layer is shown to lead to an increase in crack growth resistance. The effect of the elastic-plastic mismatch between the two materials on the crack driving force, as well as the size of the fully developed plastic zone in Ti have been quantified in this work for the first time. It is shown that incorporating a Ti layer thickness of 250 nm can improve the fracture resistance by nearly ten times compared to the initiation fracture toughness in TiN, preventing catastrophic fracture of these multi-layered films. These results will aid in physics informed design of optimised thickness of metallic interlayers in multi-layered thin films.