Micro/nanoscale spacers for enhanced thermophotovoltaic and thermionic energy conversion: a comprehensive review

Abstract: Thermionics and thermophotovoltaics are solid-state technologies that convert high-temperature heat into electricity by utilizing fundamental particles, electrons in thermionics and photons in thermophotovoltaics, as energy carriers. Both systems have the potential to achieve high efficiency and power density, contingent on the optimization of radiative/electronic energy fluxes. A critical factor in enhancing energy flux in these devices is the introduction of microscale (thermionics) or nanoscale (thermophotovoltaics) gaps between the hot thermal emitter and the cooler receiver. In thermionic converters, microscale gaps mitigate space charge effects that create energy barriers to electron flow. For thermophotovoltaic systems, nanoscale gaps facilitate photon tunneling, significantly boosting photon flux towards the thermophotovoltaic cell. Forming these small-scale gaps often necessitates intermediate materials or spacers between the emitter and receiver. Over the past few decades, various spacer designs have been proposed and studied, demonstrating their effectiveness in enhancing energy transfer and conversion. However, challenges remain regarding their reliability and scalability. This article provides a comprehensive overview of spacer technologies for thermionics and thermophotovoltaics and summarizes recent advancements, current capabilities, and persistent challenges.