Improving diffusion modeling in all-solid-state lithium batteries: a novel approach for grain boundary effects

Abstract: All-solid-state lithium-ion batteries offer promising advantages with respect to capacity, safety, and performance. The diffusion behavior of lithium ions in the contained polycrystalline solid-state electrolyte is crucial for battery function. While atomistic studies indicate that grain boundaries (GBs) and grain size significantly impact diffusivity, the corresponding effects are either neglected in simulations on larger scales or considered only under strong assumptions such as isotropy. Our approach considers the fully resolved crystalline structure with a parametrization aligned with the atomistic perspective to describe diffusion along and across GBs. The approach is embedded into a finite element simulation using a novel collapsed interface element based on an analytical description in thickness direction. Results are governed by different and potentially anisotropic diffusion coefficients in bulk and GB domains. The mesoscale response is derived using linear computational homogenization to capture large-scale effects. The novel collapsed interface description allows for a reconstruction of the 3D transport behavior within the GB domain without resolving it and is able to capture the relevant transport mechanisms such as channeling effects and concentration jumps. Grain size and GB volume fraction are expressed in terms of an affine parameter dependence and can be altered without any changes to geometry or mesh. Together with the observed dependence of the effective material response on the anisotropic GB parametrization, this leads to the identification of four distinct diffusion regimes, each with implications for the design of battery materials.