Cyclically sheared colloidal gels: structural change and delayed failure time

Abstract: We present experiments and simulations on cyclically sheared colloidal gels, and probe their behaviour on several different length scales. The shearing induces structural changes in the experimental gel, changing particles' neighborhoods and reorganizing the mesoscopic pores. These results are mirrored in computer simulations of a model gel-former, which show how the material evolves down the energy landscape under shearing, for small strains. By systematic variation of simulation parameters, we characterise the structural and mechanical changes that take place under shear, including both yielding and strain-hardening. We simulate creeping flow under constant shear stress, for gels that were previously subject to cyclic shear, showing that strain-hardening also increases gel stability. This response depends on the orientation of the applied shear stress, revealing that the cyclic shear imprints anisotropic structural features into the gel.