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Disorder-Engineered Hybrid Plasmonic Cavities for Emission Control of Defects in hBN

Published 17 Jun 2025 in physics.optics, physics.app-ph, and quant-ph | (2506.14517v1)

Abstract: Defect-based quantum emitters in hexagonal boron nitride (hBN) are promising building blocks for scalable quantum photonics due to their stable single-photon emission at room temperature. However, enhancing their emission intensity and controlling the decay dynamics remain significant challenges. This study demonstrates a low-cost, scalable fabrication approach to integrate plasmonic nanocavities with defect-based quantum emitters in hBN nanoflakes. Using the thermal dewetting process, we realize two distinct configurations: stochastic Ag nanoparticles (AgNPs) on hBN flakes and hybrid plasmonic nanocavities formed by AgNPs on top of hBN flakes supported on gold/silicon dioxide (Au/SiO2) substrates. While AgNPs on bare hBN yield up to a two-fold photoluminescence (PL) enhancement with reduced emitter lifetimes, the hybrid nanocavity architecture provides a dramatic, up to 100-fold PL enhancement and improved uniformity across multiple. emitters, all without requiring deterministic positioning. Finite-difference time-domain (FDTD) simulations and time-resolved PL measurements confirm size-dependent control over decay dynamics and cavity-emitter interactions. Our versatile solution overcomes key quantum photonic device development challenges, including material integration, emission intensity optimization, and spectral multiplexity. Future work will explore potential applications in integrated photonic circuits hosting on-chip quantum systems and hBN-based label-free single-molecule detection through such quantum nanoantennas.

Summary

  • The paper introduces a hybrid cavity design that enhances quantum emission from hBN defects using disorder-engineered plasmonic nanostructures.
  • It employs thermal dewetting and FDTD simulations to achieve size-dependent decay control and quantify up to 100-fold photoluminescence improvement.
  • The study paves the way for scalable, on-chip quantum photonics by integrating cost-effective hybrid cavities with improved emitter uniformity.

Disorder-Engineered Hybrid Plasmonic Cavities for Emission Control of Defects in hBN

The paper "Disorder-Engineered Hybrid Plasmonic Cavities for Emission Control of Defects in hBN" presents a significant advancement in the emission control of quantum emitters embedded in hexagonal boron nitride (hBN) through innovative hybrid plasmonic cavities. The primary focus is on the integration of plasmonic nanocavities with defect centers in hBN to enhance photoluminescence (PL) and manipulate decay rates without precise emitter positioning.

Key Contributions and Methodology

This study proposes a scalable, low-cost fabrication method to improve emission characteristics of defects in hBN nanoflakes. Utilizing the thermal dewetting process, two configurations are developed: stochastic silver nanoparticles (AgNPs) directly on hBN flakes and AgNPs on hBN supported by gold/silicon dioxide (Au/SiOâ‚‚) substrates forming hybrid nanocavities. The direct interaction of AgNPs with hBN results in up to a two-fold enhancement of PL alongside reduced lifetimes. However, the hybrid nanocavity architecture provides a notable up to 100-fold PL enhancement, showcasing improved uniformity across multiple emitters.

Finite-difference time-domain (FDTD) simulations accompanied by time-resolved PL measurements allow the authors to gain insights into size-dependent control over decay dynamics and cavity-emitter interactions. This comprehensive investigation addresses crucial quantum photonic device development challenges, such as emission intensity optimization and scalable material integration.

Significant Results

  • Enhancement Factors: The paper reports notable PL enhancements, with bare AgNP configurations achieving two-fold enhancement and hybrid cavities reaching up to 100-fold enhancement.
  • Photocentric Uniformity: The hybrid configuration demonstrated improved PL consistency across various emitters, a marked improvement over stochastic bare AgNPs.

Discussion

The results are particularly compelling as they address the often challenging integration of quantum emitters with plasmonic nanostructures. The stochastic nature of the dewetting process simplifies fabrication, eliminating the need for precise emitter placement. Increased PL intensity and modified decay rates are attributed to enhanced radiative processes and localized electromagnetic field confinement. However, the paper highlights the importance of emitter-nanoparticle alignment, influencing rate modifications.

Implications and Future Directions

This research positions itself as a vital component for advancing future quantum photonic applications, specifically integrated photonic circuits and label-free single-molecule detection systems. The simplicity and effectiveness of the hybrid plasmonic cavity design suggest potential applications in on-chip quantum systems, offering practical insights for scalable quantum device fabrication.

Potential future work includes exploring diverse emitter environments in hBN, further refining the coupling mechanisms for enhanced control over emission spectra and decay dynamics. The developments may eventually lead to more sophisticated and adaptable quantum photonic circuits.

In summary, this paper makes substantial contributions to the understanding and application of hybrid plasmonic cavities in quantum photonics, establishing a pathway for practical emitter enhancement in hBN that could be integral to future quantum technology research and development.

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