Theoretical study of transition energies and matrix elements of the cadmium atom

Abstract: The relativistic Fock-space coupled-cluster methods are applied to the cadmium atom. A large number of transition energies and matrix elements are calculated for the $5s^{2}:$$ ^{1}S \to 5snp: ^{1,3} P^{o}$, $5s6s: ^{1}S \to 5snp: ^{1,3} P^{o}$ and $5s5d: ^{1}D \to 5snp: ^{1,3} P^{o}$ transitions for a wide range of $p$ states accounting for relativistic and electron-correlation effects. The results obtained within two different approaches (Fock-space coupled cluster and configuration interaction) are compared with available experimental and theoretical data. Good agreement is found between the two methods for transitions involving low-lying excited $p$-states, whereas for high-lying states, the discrepancy becomes large. The calculated values are used to determine the third-order nonlinear susceptibility of cadmium vapor, with an agreement within 5\% between the different methods. The results of the present computations support the feasibility of generating vacuum ultraviolet light in Cd vapor via a four-wave mixing process for the spectroscopy of $^{229}$Th isomer transition.