Deep ultraviolet resonant Raman (DUVRR) spectroscopy for spectroscopic evaluation and disinfection of food and agricultural samples

Abstract: The increasing demands on modern plant and food production due to climate change, regulatory pressures, and the Sustainable Development Goals necessitate advanced photonic technologies for improved sustainability. Deep ultraviolet resonant Raman (DUVRR) spectroscopy offers precise spectral fingerprinting and potential disinfection capabilities, making it a promising tool for agricultural and food sciences. We developed a cost-effective, portable DUVRR spectroscopy system using a mercury (Hg) lamp as the excitation source at 253.65 \unit{\nano\meter}. The system was tested on diverse samples, including alcohol solvents, organic extracts, and industrial chemicals. The DUVRR system successfully resolved sub-1000 \unit{\per\centi\meter} Raman peaks, enabling detailed spectral fingerprints of various constituents and biomarkers. The system's high sensitivity and specificity ensure precise identification of nutritional values and food quality. The DUV light used in the system, defined here as less than 260 \unit{\nano\meter}, demonstrated potential disinfection properties, adding significant value for food safety applications. The highly sensitive detection capability of our DUVRR system at low powers has significant implications for plant and agricultural sciences. The detailed spectral information enhances the evaluation of nutritional values, food quality, and ripening processes. This dually-functional system is highly valuable for precision farming, food production, and quality control. Our DUVRR spectroscopy system provides a highly sensitive, affordable, and portable method for the spectroscopic evaluation and disinfection of food and agricultural samples. Its ability to resolve detailed Raman peaks below 1000 \unit{\per\centi\meter}, combined with DUV light's disinfection capabilities, makes it a promising tool for advancing sustainability and safety in agriculture and food production.