Modulation of Non-equilibrium Structures of Active Dipolar Particles by an External Field

Abstract: We study the impact of an external alignment field on the structure formation and polarization behavior of low-density dipolar active particles in three dimensions. Performing extensive Brownian dynamics simulations, we characterize the interplay between long-range dipolar interactions, field alignment, and self-propulsion. We find that the competition between activity (favoring bond breaking) and the field's orientational constraint (promoting bond formation) gives rise to a rich variety of self-assembled, actuated structures. At low to intermediate field strengths, disordered fluids composed of active chains and active percolated networks can emerge, whereas strong fields drive the formation of polarized columnar clusters. Counterintuitively, low activity levels significantly extend the range of field strengths over which percolated networks persist. This structural evolution manifests in the polarization response of strongly dipolar systems, which exhibit a transition from super-Langevin to sub-Langevin behavior with increasing activity, as a result of the coupling between structure formation and activity-induced bond breaking.