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Non-equilibrium thermodynamics of the quantum Brownian motion: Anomalous non-equilibrium currents arising from complete positivity

Published 31 Jul 2025 in quant-ph and cond-mat.stat-mech | (2507.23322v1)

Abstract: We rigorously analyze the non-equilibrium thermodynamic behavior of various formulations of quantum Brownian motion (QBM) using the framework of stochastic thermodynamics. While the widely used Caldeira-Leggett master equation exhibits desirable thermodynamic features, such as the fulfilment of a detailed balance, it fails to ensure complete positivity. In contrast, several completely positive and trace-preserving (CPTP) extensions turn out to be thermodynamically controversial. We show that such extensions introduce anomalous phase-space structures that violate detailed balance at the steady state, leading to non-vanishing entropy production and effective non-equilibrium current of unclear physical origins. Our results highlight a fundamental tension between quantum consistency and thermodynamic equilibration in open quantum systems.

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