Capillary currents and viscous droplet spreading

Abstract: We present the results of a combined experimental and theoretical study of the spreading of viscous droplets over rough and smooth substrates. First, we experimentally investigate the wetting of a roughened glass surface by a viscous droplet of silicone oil, wide and shallow relative to the capillary length $\ell_c$. The radius of the droplet grows according to a $R_\mathrm{drop}\sim t^{1/8}$ scaling reminiscent of gravity currents (Lopez, 1976; Voinov, 1999). The droplet is preceded by a mesoscopic fluid film that percolates through the rough substrate, its radius increasing according to $R_\mathrm{film}\sim t^{3/8}/(\log t)^{1/2}$. To rationalize these observed scalings, we develop a new 'capillary current' model for the spreading of shallow droplets with arbitrary radius on both smooth and rough surfaces. We propose that, throughout their evolution, capillary currents maintain a quasi-equilibrium balance between hydrostatic and curvature pressure, perturbed only by unbalanced contact line forces arising along the droplet's edge. In addition to rationalizing our experimental data, our model provides new rationale for a number of scalings reported in prior work. In particular, for drops small with respect to $\ell_c$, it recovers the classic spreading laws of Tanner (1979) and Hoffman (1975); for drops wide with respect to $\ell_c$, it reveals how millimetric, surface-tension-driven capillary currents exhibit the same spreading behavior as relatively large-scale viscous gravity currents.