Engineering Near-Infrared Two-Level Systems in Confined Alkali Vapors

Abstract: We combined experimental and theoretical investigations of an effective two-level atomic system operating in the near-infrared telecom wavelength regime, realized using hot rubidium vapor confined within a sub-micron-thick cell. In this strongly confined geometry, atomic coherence is profoundly influenced by wall-induced relaxation arising from frequent atom-surface collisions. By analyzing both absorption and fluorescence spectra, we demonstrate that the optical response is dominated by a closed cycling transition, which effectively isolates the atomic dynamics to a two-level configuration despite the presence of multiple hyperfine states. This confinement-induced selection suppresses optical pumping into uncoupled states and enables robust, controllable light-matter interaction at telecom wavelengths within a miniature atomic platform. Our results establish a practical route to realizing near-infrared atomic two-level systems in compact vapor-cell devices, opening new opportunities for integrated quantum photonic technologies, including on-chip quantum memories, telecom-band frequency references, and scalable quantum information processing.