Thermodynamics of the Heisenberg XXX chain with negative spin

Abstract: We study the thermodynamics of the isotropic Heisenberg XXX spin chain with negative spin, focusing on the case $s=-1$. The model is equivalent to the quantum lattice nonlinear Schrödinger (NLS) model and appears as an effective theory in deep inelastic scattering in high-energy quantum chromodynamics. Owing to its integrability, it admits a consistent Bethe Ansatz description and a well-defined thermodynamic limit. Using the thermodynamic Bethe Ansatz, we analyze the ground state, elementary excitations, and finite-temperature properties. In contrast to the conventional positive spin XXX chain, the negative spin model exhibits a distinct vacuum structure and excitation spectrum, leading to modified TBA equations and unconventional low-temperature behavior. Although the integral equations resemble those of the Lieb-Liniger Bose gas, the thermodynamics and scaling properties are qualitatively different and cannot be continuously connected. We derive the free energy, entropy, and specific heat, and identify a quantum phase transition separating different thermodynamic regimes. At zero temperature, the excitation spectrum becomes linear in the continuum limit and can be described by a conformal field theory. The low-temperature regime realizes a Luttinger-liquid like phase with features unique to the negative spin XXX chain.