Analytic evaluation of Doppler-averaged V-type double-resonance lineshape beyond the weak-pump–weak-probe limit
Derive a closed-form analytic expression for the velocity-averaged probe absorption (or upper-state population) in V-type optical–optical double resonance by integrating the steady-state solution over the thermal velocity distribution. Specifically, evaluate ∫_{−∞}^{∞} ρ33^{V}(Δω21 + k_a v_z, Δω23 ± k_b v_z) dv_z beyond the weak-pump–weak-probe limit, in particular for saturated pumping or the weak-probe approximation, where ρ33^{V} denotes the V-type three-level steady-state result with equal relaxation rate γ.
References
As for the ladder-type DR case, Mathematica was not able to produce analytical results for integration over $v_z$ except for the weak pump and probe limit.
— Theory of Lineshapes in Optical-Optical Double Resonance Spectroscopy
(2604.02262 - Lehmann, 2 Apr 2026) in Section “V-type Double resonance,” discussion following Eq. (\ref{eq:rhoVwpp33})